An blue screens or just system freezes? (blue screens may offer some clues as to the cause). Absent more detail one can only just guess. When I've had freezes on boot up generally my CPU has been undervolted. Suggest booting into bios and double check that CPU voltage is set to Manual and Auto. Also check that your RAM voltage is correct (likely 1.5v or 1.65v - kit dependent). And that the reported voltage for your RAM = the set value. If not then make the necessary small adjustment. For instance I need to set 1.510v to actually achieve 1.5v actual. Are you using XMP settings for your RAM? If yes then check to see if you need a specific Vccsa voltage. For my kit under XMP I need 1.1v. Make that adjustment if needed. Finally check your c-states are set to Auto.
Some drivers can also create issues, I have had trouble with 2 in particular. The RST driver and the Asmedia USB3 driver. If running windows 10 then use the default drivers that come with the OS. If stiil on windows 7 try a v13.xx version of the RST driver and use the last Asmedia driver posted on the ASUS support site for the R4BE or RIVE. Version 30 something or rather.
Hope something here helps.
MB : Rampage IV BE. - Bios 0801
CPU : i7 3970x @ 4500 MHz, Offset +0.030v, Regular LLC, Fixed Frequency 750, C1E Enabled, C3/C6/C7 Disabled
CPU VCCSA: Manual 1.150v, Regular LLC, Fixed Frequency 500
RAM : Corsair Vengeance @ 1866 MHz - 64GB
Disks : Raid0 2x Intel 520 480GB; 2x Seagate 2TB
GFX : EVGA GTX690
Audio : Creative X-FI Titanium HD
PSU : Corsair AX1200i
Optic BD\DVD : Lite-On Blu-Ray; Samsung DVDRW
Cooler\Case : Corsair H100i v2 2; Silverstone TJ07
OS : Win10 Pro 64