Hi nailmaker,
According to our manual, PCIEX16_3 shares bandwidth with SATA6G_12 and SATA6G_34. When PCIEX16_3 runs at x4 mode, both SATA6G_12 and SATA6G_34 are disabled.
(Please refer to the page vii, xiv.)
Moreover, M.2_2 shares bandwidth with PCIEX16_1 and PCIEX16_2. When M.2_2 is enabled, PCIEX16_1 will run at x8 mode and PCIE_16_2 will run at x4 mode.
(Please refer to the page viii, xiii.)
https://dlcdnets.asus.com/pub/ASUS/mb/LGA1200/ROG_MAXIMUS_XIII_HERO/E18089_ROG_MAXIMUS_XIII_HERO_UM_...Thank you.