OK so to start there is no guarantee you can use all the sticks together. We can of course try to work it out.
First thing i would do is to take all the sticks out and separate the two kits...there should be serial numbers on the sticks which will let you know which two sticks are one kit.
When you have done that use one kit on the recommended slots and see if you can run XMP.....if you can all good, swap out one kit for the other and see if that second kit will run XMP....if so OK.
When you do this take a look in the RAM timings subsection ( DRAM Timing Control) of the BIOS and take a note of the settings of the primary timings that XMP sets...
I think it will be 11-13-14-
?-
?T (need to know the question mark values)
With those timings we can try and set the RAM up manually...
Can you also scan down secondary and tertiary timings to see if they are the same for both kits!
In Extreme Tweaker menu set AI Overclock tuner to Manual, set DRAM Frequency to 2400, go into RAM timings and manually enter primary timings 11-13-14-
?-
?T (leave everything else on auto), set DRAM voltage Vdimm or whatever it's called to 1.65v for all channels...
Can you also see what the board is setting for "CPU system agent voltage" at XMP....