Hi Santi,
First of all, welcome to the ROG forum!
🙂 I would highly recommend that you stay under 1.25 vcore for the i5-4690K. What idle and load temps are you getting right now at 1.3V? Overclocking is quite safe now that even if your vcore is slightly higher, it shouldn't pose any danger to your CPU as long as you stay under 80 degrees. On air, 80 degrees is definitely the target but since you're using an AIO liquid cooler then you have a little bit more room to play with.
There's a very helpful overclocking video that Linus did, you can check it out and see if it helps you:
https://www.youtube.com/watch?v=0CHs5_TdpXECheers,
Bahz