Small update (if you're interested), as I only had about 90 minutes last night to carry on I can't confirm long term stability yet, but...
BIOS recognised all 32GB, originally as 1333mhz as XMB was not enabled. I manually entered the memory frequency and timings and it accepted it all at boot without any issues. Left everything at stock frequencies for the moment. Card works fine in the other PCI-E x16 slot so it doesn't appear to require the primary, although this will be a problem once in SLI. Installed windows 8, board software/drivers and part way through installing my usual list of programs.
Next up: BIOS update to 3404 (currently at 3204), Memtest, benchmarking and general stability checking. Completing program installs. Then I'll start seeing how far I can push the RAM clocks and the CPU on air (the cooler is flipping huge so hopefully quite a way!).
So far it's looking good, but it's early days.
In the future then, would you recommend changing to some higher clock rated Dominators? I like Corsair as I've always had good experiences with their chips, but I'm not blindly devoted if there's a much better option.
EDIT: Oh yes, one more thing. I've taken the SSDs out of RAID0. No TRIM support apparently, so will be more efficient to leave it as a single 256GB drive rather than a raided 512. Oh well.
Intel 3930K CPU overclocked and stable at 4.6GHZ
Corsair H100i closed loop waterblock for CPU
Asus Rampage IV Extreme motherboard
32GB Corsair Dominator RAM (4 * 8GB @ 1866MHZ, CAS9)
2x GeForce 780 GTX in SLI
Samsung 830 256GB SSD
Samsung 840 Pro 512GB SSD
Antec 1200 V3 case
SilverStone Strider ST1500 1500W PSU
3 x HN274H bmiiid 27" 120HZ 3D Monitors
Synology DS1512+ (5 x 3TB WD Red RAID 6)
Razer Black Widow Ultimate 2013 & Mamba 2012
Sennheiser PC 363D and Razer Tiamat 7.1 Headsets