On the Asus R4E:
- the X79 chipset provides two red SATA6Gbps ports and four black SATA3Gbps ports, which all support RAID(0,1,5,10).
- the ASMedia chipset adds two red SATA6Gbps ports and two red eSATA6Gbps ports, which all support AHCI only.
At most you could make a bootable 2xSATA6 RAID, a bootable 4xSATA3 RAID, and (on the ASMedia ports) a nonbootable 2xSATA6 software RAID. PCIe-based storage devices can only be configured within nonbootable software RAIDs, unless they happen to interface directly into the X79 SATA ports.
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[/Korth]