from MVE manual, page 1-26 "PCIe 3.0/2.0_x8_2B slot will be disabled when PCIe 3.0/2.0_x16_2A, PCIe 3.0/2.0_x8_3, PCIe 3.0/2.0_x8_4 slots are occupied."
Having 680 SLI in slots 1 & 4 does just that, it disables 2B.
.: R3C0NF1GUR3D :.ASUS MVE :: 3770K bench @ 5.2GHz (delidded) :: 2x4GB Mushkin 996990 @ 2400MHz CL10 @ 1.7V :: evga 670 2GB SLI @ 1280/7108 :: Mushkin Chronos 240GB SSD RAID0 (OS) :: WD RE4 2TB (storage) 2TB :: Hitachi Deskstar 5K300 2TB (backup USB3.0) :: ASUS VG248QE 24'' 144Hz monitor
My rig with pictures"We are what we repeatedly do. Excellence, then, is not an act, but a habit." - Aristotle