Do you mean the 'GO' led, that enables MEMOK (blinking, MEMOK enabled), or the DRAM Q LED. I would clear the BIOS before doing anything else. Did it ever work or has it been this way since first boot. What Q code are you getting?
Install 1 stick of ram only and try to boot. Try each of them and see what happens. I would use slot A2. Also, make sure that your CPU cooler is mounted solidly against the CPU (good mount), which leads me to also suggest you verify that you have no bent CPU socket pins.
Current rig:
Asus MVE/32gb Trident-X 2400/1 Muskin Atlas MSATA 240gig - Win 7 Ultimate/2x Segate 3tb 7200rpm, 1 WDB 1tb (data backups)/1 PCIE SB Fatality/3770k delidded at 4.8ghz/2x EVGA 580 3gig (not yet on water)/2x LG BD burners/Water- Raystorm block, Rad-XSPC RX360v2, Res-Alphacool dualbay Repack w/D5vario, on distilled./PSU Corsair 1200i/NO case- on a 6' metal shelving unit, also holds my server, and drawers w/spare parts./46" Samsung SmartTV UN46ES7100.