No Worries mate! It was great to get some support with my problem.
Even though the original answers didnt solve the problem, they did help me narrow down where to look and eventually uncover the culprit!
System has been rock solid since, in fact probably the most stable its ever been, without a single crash during many hours of maxed GPU usage.
That original cable with the melted ez-plug PCIE cable was actually a factory Enermax PSU cable and the only cable I didnt make from scratch! I upgraded all of the wiring in my custom cabling by at least 1 gauge of wire from what Enermax used as well because I knew I was going to be pushing it hard and wanted minimal voltage drop! 🙂