So after I did a reinstall of my armoury crate, to the best of my ability (Because for some reason its a massive pain in the ass I will only do it as an absolute last resort to fixing something). My Rog key that used to open the armoury crate no longer works (all my other hotkeys do though).
The key does appear to switch to the armoury crate program when its open, it just wont launch it. Heres the list of service versions according to armoury crate
Armoury Crate UWP App 184.108.40.206
ROG Live Service 220.127.116.11
AURA Service (Lighting Service) 3.04.15
Armoury Crate service 3.0.4
ASUS Aac_NBDT HAL 18.104.22.168
ASUS Keyboard HAL 1.0.50
ASUS MB Peripheral Products 1.0.31
ASUS Mouse HAL 1.0.50
Nevermind Apparently if you disable armoury crate App Execution Alias the Hotkey stops working to launch the program but it works to 'focus' it.